Hi Jgazal,
First of all, I'm not an EE. All I can tell you is from my experience making my own electrostatic headphones.
You might have been confused about the earphone's drivers and the cup. The purpose of the earcup is simply to hold the driver in its proper place. Since you are dealing with high voltage, you want to make sure that the high voltage will not be able to do any harm to the person who wears the headphones. If you look inside Stax headphones, you would see a plastic enclosure holding the driver rigidly and tightly together. This is also made of plastic which is a good insulator.
I can't speak for Stax, but my guess is that Stax has changed the earcup from plastic to aluminum because it simply looks and feels much better. I don't think it has anything to do with electrostatic discharge.
Wachara C.